University Physics Notes: Quantum Mechanics – The Schrodinger Equation
The general equation expressing the conservation of energy of a
particle in classical mechanics is
In
quantum mechanics we have something very similar, with the
intoduction of a concept called the wavefunction.
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or equivalently![]()
The first of these is called the time independent Schrodinger equation. Time does not appear anywhere in the equation. E on the right hand side is the energy and this equation fully expresses the principle of conservation of energy
The time independent Schrodinger equation allows for the evolution
of the wavefunction in time. In general the wavefunction may consist
of two parts – the space part and the time part. The space part
is
a function of position only and the time part is a function of time
only,![]()
The Schrodinger equation has several important properties.
It is linear. This means that if
and
are
solutions then so is
and
by extension, any linear combination of solutions is also a
solution.
The equation is second order. This means that given a
potential function
in
a region, we can solve the equation to find the general solution,
but this solution generally contains two arbitrary constants A and
B. To find these two arbitrary constants, we need exactly two
initial conditions or more typically, boundary conditions or
physical constraints to find the constants A and B. The physical
constrain may be that the solution must tend to zero as
tends to![]()
Because the Schrodinger equation is second order any
solution
or
first differential
must
be continuous across a physical boundary. Essentially this mean we
can join up the wavefunction on either end of a boundary so that at
the boundary both the wavefunction and it's first derivative have
the same value.