University Physics Notes: Quantum Mechanics – The Bohr Model of the Hydrogen Atom
Bohr made the major innovation of hypothesising the quantization
of angular momentum in units of
where
This
means we can write![]()
We can use the ordinary rules of classical Newtonian mechanics to derive the equation giving the differences in the energy levels of the electrons in the Hydrogen atom.
We can equate the Coulomb force to the force required to keep the electron in orbit around the nucleus.
![]()
From this we can obtain
(1)
and
(2)
The total energy of the electron in it's orbit is the sum of the kinetic and potential energies: Use of (2) gives
![]()
This means an energy change of
where
is
the frequency and
is
the wavelength of the associated emitted or absorbed photon.
Substitute (1) to give
![]()
Use
this and divide by
to
get
![]()
is
called the Rydberg constant and is given the symbol
It
has the value![]()