University Physics Notes: Quantum Mechanics – Properties of the Eigenfunctions
The eigenfunctions
are
the solutions of the eigenfunction equation
the
solutions
for
the one dimensional simple harmonic oscillator case, are polynomials
in
multiplied
by a gaussian
If
the
are
normalized to unity they have the following properties:
The
are
orthonormal This means that
(1)
where
is
the Kronecker delta, defined by
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The
form
an abstract vector space. Any arbitrary wavefunction can be
expressed in terms of the eigenfunctions
We
can write
(2)
or using the abstract vector space properties of the
we
can write
as
a column vector:
with
the property that

In this expression the
are
the coefficients of the eqienfunctions in the expression (2), and
the position in the ith row signifies the ith eigenvector. It must be
understood here that the vector space usually has infinite dimension.
Because we can write the wavefunction as a column vector, we can
operate on it with a matrix like any other vector.
For the one dimensional case, as
This
is necessary so that the eigenfunction can be normalized.
is
real for the one dimensional harmonic oscillator,
is
real for the two dimensional harmonic oscillator and
is
real for the three dimnsional harmonic oscillator.
is
real for the hydrogen atom, and in fact for all stationary state
eigenfunctions. Each of these may be multiplied by a time term
and
in the case of the hydrogen atom, an angular term which is complex
in general, to obtain the state function
which
is a function of t and other space variables
Each
of these factors is normalised to 1.
Given a wavefunction
we
can find the coefficients
using
that all the
are
orthogonal.
![]()
Take the dot product with![]()
since
being
normalized, hence![]()
The dot product here is the generalized dot product – it could be an integral for example as in (1).