University Physics Notes: Quantum Mechanics – Expectation Values



If we have a list of possible outcomeswith the probability of each possible outcome beingthen the value ofwe would expect to get, averaged over many trial is If the possible outcomes is not in the form of a list of discrete values but a range, so thatmay take any value between certain limitsthe we evaluate an integral. In this case where the range of possiblevalues is

In quantum mechanics we have something similar. Remember that the probability density of a particle is given by

whereis the operator of the observable we want to find the expectation value of.

For example ifthe expectation value of the position is

We use the identity,rearranging to obtainThe integral becomes

We integrate by parts:

This is, as we would expect in the centre of the well, sinceis symmetric about the centre of the well.

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