University Physics Notes: Quantum Mechanics – Expectation Values
If we have a list of possible outcomes
with
the probability of each possible outcome being
then
the value of
we
would expect to get, averaged over many trial is
If
the possible outcomes is not in the form of a list of discrete values
but a range, so that
may
take any value between certain limits
the
we evaluate an integral. In this case
where
the range of possible
values
is![]()
In quantum mechanics we have something similar. Remember that the
probability density of a particle is given by![]()
where
is
the operator of the observable we want to find the expectation value
of.
For example if
the
expectation value of the position is
![]()
We use the identity,
rearranging
to obtain
The
integral becomes
![]()
We integrate by parts:![]()
![]()
![]()
![]()
This is, as we would expect in the centre of the well, since
is
symmetric about the centre of the well.