University Physics Notes: Quantum Mechanics – Dispersion Relations
A particle does not occupy a fixed, definite position in space. It is smeared out over a definite none zero volume in the form of a wave packet.
In general the wavepacket is maade of of many different frequencies or wavelengths. The intefere constructively in the region of the particle and destructively outside it. Different parts of the wavepacket will in general travel at different velocities, with the velocity dependant on frequency or wavelength. This means that the wavepacket will spread out as it travels. We can derive the 'disperson relation' from the wave obeyed by the particle.
The basic, non – dispersive wave equation is
or
(1)
in one dimension. This equation is obeyed only by ideal waves –
which have no weight, for example. Electromagnetic waves travelling
through a vacuum obey this form of wave equation.
If the conditions of ideality do not apply
for example if the wave is carried by a string which is not
perfectly flexible, then we will need to introduce a term
proportional to displacement with a negative coefficient. The wave
equation becomes
(2)
or the wave is moving through a resistive medium, so experiences
damping, we need to introduce a term proprtional to {partial y} over
{partial t} with a negative coefficient. The wave equation becomes
(3)
The dispersion relation is found by substituting the solution for
the undamped wave equation (1)
(4)
into (2) or (3). Dividing by the exponential factor leaver leaves the
dispersion relation.
For the first example (2)
Differentiating (4) gives![]()
Subsitution into (1)
![]()
Dividing by the non zero
gives
or![]()
The phase velocity
and
the group velocity
For the second example (3)
![]()
Dividing through by
as
before gives
The
complex factor here is a problem. It means that either
or
is
complex. Because we included a damping or resistance term
differentiated with respect to time, I will assume it is
that
is complex, that![]()
![]()
![]()
Cancelling the exponential term gives
![]()
Equating the real parts gives![]()
Equating imaginary parts gives![]()
![]()
![]()
