University Physics Notes: Quantum Mechanics – Dispersion Relations



A particle does not occupy a fixed, definite position in space. It is smeared out over a definite none zero volume in the form of a wave packet.

In general the wavepacket is maade of of many different frequencies or wavelengths. The intefere constructively in the region of the particle and destructively outside it. Different parts of the wavepacket will in general travel at different velocities, with the velocity dependant on frequency or wavelength. This means that the wavepacket will spread out as it travels. We can derive the 'disperson relation' from the wave obeyed by the particle.

The basic, non – dispersive wave equation isor (1) in one dimension. This equation is obeyed only by ideal waves – which have no weight, for example. Electromagnetic waves travelling through a vacuum obey this form of wave equation.

If the conditions of ideality do not apply

for example if the wave is carried by a string which is not perfectly flexible, then we will need to introduce a term proportional to displacement with a negative coefficient. The wave equation becomes (2)

or the wave is moving through a resistive medium, so experiences damping, we need to introduce a term proprtional to {partial y} over {partial t} with a negative coefficient. The wave equation becomes (3)

The dispersion relation is found by substituting the solution for the undamped wave equation (1) (4) into (2) or (3). Dividing by the exponential factor leaver leaves the dispersion relation.

For the first example (2)

Differentiating (4) gives

Subsitution into (1)

Dividing by the non zerogivesor

The phase velocityand the group velocity

For the second example (3)

Dividing through by as before givesThe complex factor here is a problem. It means that eitheroris complex. Because we included a damping or resistance term differentiated with respect to time, I will assume it isthat is complex, that

Cancelling the exponential term gives

Equating the real parts gives

Equating imaginary parts gives

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