A Level Physics Notes: Thermal Physics and Gases - Heat Engines and Entropy


A heat engine is a system that transfers heat from a hot to a cold
body, and uses some of the heat to do useful work. Not all of the
heat can be converted into useful work, and in fact there is a
theoretical limit to the efficiency of a heat engine in per cent,
given by
As
energy is transferred the entropy of each body changes, with the
entropy change given by
The
entropy change is positive if a body gains energy because
is
positive, and negative if a body loses energy because
is
negative.
In the above machine
and
The
efficiency of the above machine is the maximum possible at 40%. The
entropy change of the machine is
The
over entropy change is not zero however because 160J is transferred
to the surroundings, and will increase the entropy of the
surroundings because
is positive for the surroundings. If the machine is less efficient
that the perfect heat machine, the entropy of the machine itself will
increase since more heat will be transferred to the cold reservoir,
so it's entropy will in crease by more and energy will still be
transferred to the surroundings, so increasing their entropy.